An absorptive chemically induced dynamic electron polarization (CIDEP) was generated by the quenching of singlet oxygen by nitroxide radicals (TEMPO derivatives). The spin polarization decay time of the nitroxide (measured by time-resolved EPR) correlates with the lifetime of singlet oxygen (measured by singlet oxygen phosphorescence spectroscopy). In addition, a deuterium isotope effect on the...

We discuss electron-electron contact-interaction searches in the processes ee → ee and e−e− → e−e− at planned Linear Colliders run in the ee and e−e− modes with both beams longitudinally polarized. Our analysis is based on the measurement, for the two processes, of polarized differential cross sections, and allows to simultaneously take into account the general set of electron contact interacti...

the kinetics of hydrogen evolution reaction (her) was studied in 1m naoh at various temperatures (298 to 358 k) on ni-p-c (composite electrodes. the electrochemical efficiency of the electrodes has been evaluated on the basis of electrochemical data obtained from the steady-state polarization tafel curves, electrochemical impedance spectroscopy (eis) and cyclic voltammetry (cv) in 1m naoh solut...

The modern quantum theory of polarization in dielectrics has been formulated only in recent years [1]. This development has opened a new era in the first principles theory of ferroelectricity and pyroelectricity [2]. The new theory has been used successfully to calculate, in a well defined and computationally efficient way, the macroscopic polarization changes induced by perturbations other tha...

The instrumental polarization induced by a flat isotropic dielectric slab in microwave frequencies is discussed. We find that, in spite of its isotropic nature, such a dielectric can produce spurious polarization either by transmitting incoming anisotropic diffuse radiation or emitting when it is thermally inhomogeneous. We present evaluations of instrumental polarization generated by materials...

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A simplified phase-cycling scheme for heteronuclear active-coupling-pattern tilting (ACT) spectroscopy is presented. It is demonstrated that the theoretically expected twofold sensitivity gain over earlier implementations can be experimentally realized. A further intensity increase by a factor of 2 is obtained with standard sensitivity-enhancement pulse-sequence elements. The HSQC-HECADE sequen...

An analysis is presented of optical absorption and emission in semiconducting, metallic, and mixed coreshell nanowires are considered theoretically. Due to image forces caused by the difference in dielectric constants between nanowires and their environment, absorption and emission coefficients are different for light polarized parallel or perpendicular to the nanowire axis. As a result, the in...

In this article, corrosion behavior of the single-layered TiN, single-layered CrN and multi-layered TiN/CrN coatings have been fabricated on 420C stainless steel (SS) by Cathodic Arc Evaporation (CAE) method in Ringer's solution was studied. The electrochemical appraisal was done by the Potentiodynamic Polarization (PDP) and Electrochemical Impedance Spectroscopy (EIS) tests. Results of PDP tes...