A new class of salicylaldiminato tin(II) catalysts having different alkoxy side chains has been developed. The ligands were modified to have different lengths and flexibilities such as –(CH2)2– (2a), –(CH2)3– (2b), –(ortho-C6H4)CH2– (2c) and –(CH2)2–O–(CH2)2– (2d). Complexes 2a, b were characterized crystallographically revealing a more constrained environment around the metal in complex 2a. Th...

Epsilon poly-L-lysine (ε-PL) is a homo-biopolymer with approximately 25-30 L-lysine residues. It is a promising natural biopolymer widely used in food and pharmaceutical industry. The present work reports enhanced production of ε-PL with a novel producer Bacillus cereus using amino acids and TCA cycle intermediates in the fermentation medium. Among the various amino acids and TCA cycle intermed...

A significant Fourier transform (SFT) algorithm, given a threshold τ and oracle access to a function f , outputs (the frequencies and approximate values of) all the τ -significant Fourier coefficients of f , i.e., the Fourier coefficients whose magnitude exceeds τ‖f‖2. In this paper we present the first deterministic SFT algorithm for functions f over ZN which is: (1) Local, i.e., its running t...

An enzymatic reaction rate of glucose oxidase (GOD) using ferricyanide ion ([Fe(CN)(6)](3-)) as an oxidant significantly increased by the addition of ε-poly-L-lysine (ε-PL). The bimolecular rate constant between GOD and [Fe(CN)(6)](3-) in the presence of ε-PL reached about 10000-fold relative to what it was measured without the ε-PL, and the Michaelis constant decreased. The reaction rate reach...

Biomedicine requires materials able to respond specific needs without affecting the organism. Organic–inorganic fibrillar polymeric matrices possess unique properties that may fulfill these needs. In present study, different topology-controlled poly(ε-caprolactone)-based containing glycine betaine at varying concentrations (0.5, 1, and 2% w/v) were prepared via electrospinning. The used as subs...

Biocomposite scaffolds were fabricated by incorporation of nanobredigite (n-BD) into the polymer of poly(ε-caprolactone)-poly(ethyleneglycol)-poly(ε-caprolactone) (PCL-PEG-PCL). The results revealed that the addition of n-BD into PCL-PEG-PCL significantly improved water absorption, compressive strength, and degradability of the scaffolds of n-BD/PCL-PEG-PCL composite (n-BPC) compared with PCL-P...

An investigation of the influence of droplet size conditions and monomer choice on electrospun carbon nanofiber properties is presented. Monomer choices included poly (ε-caprolactone) and poly (methyl methacrylate) with and without the addition of single walled carbon nanotubes. A key property under investigation is the effect of electrospinning conditions on the resulting carbon nanofiber elas...