Thermally stable dual emission followed by white-light luminescence from hybrid materials is reported. Hybrid films were prepared with a spin-coating method the mixture solution containing tetraphenylethene (TPE)-integrated polyhedral oligomeric silsesquioxane (POSS) and poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylene vinylene] (MEH-PPV). TPE-tethered POSS (TPE-POSS) showed high compatibility...

Abstract The largely demand in continued security issues makes necessary the development of novel materials with outstanding properties to improve current detection techniques. In this context, latent fingerprint (LF) by fluorescent labeled (FLM) is one most attractive personnel identification methodologies. Here, two FLM based on polyhedral oligomeric silsesquioxane (POSS) nanohybrids dansyl c...

The octa-functionalized polyhedral oligomeric silsesquioxane (POSS) containing nanocomposites of epoxy resin are prepared via in situ co-polymerization of epoxy resins with 4,4’-diaminodiphenylsulfone (DDS) in the presence of octaaminophenyl silsesquioxane (OAPS). Two of the most common, technologically relevant epoxy resins, diglycidyl ether of bisphenol-A (DGEBA) and tetraglycidyl diamino dip...

A novel luminescent polyhedral oligomeric silsesquioxane (POSS) containing in the structure a fluorescein derivative molecule and a carboxylic functionality, suitable to anchor different organic compounds (dyes, markers, drugs, contrast agents, …), was successfully synthesized and characterized in this manuscript by a multidisciplinary approach. An emission enhancement of the dye of ca. four ti...

In this study, we report UV-MALDI-TOF MS evidence of a fullerene-like silsesquioxane, a high-symmetry polyhedral oligomeric silsesquioxane (POSS or SSO) formulated as R60-Si60O90 or T60 (T = RSiO1.5). The T60 preparation can be performed using a normal hydrolytic condensation of [(3-methacryloxy)propyl]trimethoxysilane (MPMS) as an example. Theoretically, four 3sp3 hybrid orbitals (each contain...

Self-assembly of functionalized nanoscale building blocks is a promising strategy for "bottom-up" materials design. Recent experiments have demonstrated that the self-assembly of polyhedral oligomeric silsesquioxane (POSS) "nanocubes" functionalized with organic tethers can be utilized to synthesize novel materials with highly ordered, complex nanostructures. We have performed molecular simulat...

This study aims at the testing of various low-k insulators deposited at temperatures below approximately 160 C for possible application in temperature-limited copper interconnects (e.g., in plastic electronics). Various polymers were tested such as the well-known poly(methyl methacrylate) (PMMA), a Polyhedral Oligomeric Silsesquioxane (POSS) based copolymer partially fluorinated (POSS-F) and th...

We present the relaxation dynamics of glass-forming glycerol mixed with 1.1 nm sized polyhedral oligomeric silsesquioxane (POSS) molecules using dielectric spectroscopy (DS) and two different neutron scattering (NS) techniques. Both, the reorientational dynamics as measured by DS and the density fluctuations detected by NS reveal a broadening of the α relaxation when POSS molecules are added. M...

As the scientific community develops the ability to create composites which incorporate nanoscopic filler particles, the detailed atomic arrangement and atomic interactions become significant in determining the composite properties. Nanoscopic fillers such as carbon nanotubes, polyhedral oligomeric silsesquioxane (POSS), and layered silicates have already been successfully used to improve the t...