A new empirical technique to construct predictive models of vacuum pyrolysis process is presented in this study. Pyrolysis of biomass for preparing bio-oil was studied on a vacuum pyrolysis system, where rape straw was chosen as the raw material. The experiments ran based on orthogonal experimental design method. The operation factors of the system including pyrolysis temperature, system pressu...

Biomass pyrolysis with biochar returned to soil is a possible strategy for climate change mitigation and reducing fossil fuel consumption. Pyrolysis with biochar applied to soils results in four coproducts: long-term carbon (C) sequestration from stable C in the biochar, renewable energy generation, biochar as a soil amendment, and biomass waste management. Life cycle assessment was used to est...

Title of Document: CO-SOLVENT ASSISTED SPRAY PYROLYSIS FOR THE PREPARATION OF METAL MICROPARTILCE. Kai Zhong, Doctor of Philosophy, 2012 Directed By: Professor Sheryl H. Ehrman, Department of Chemical and Biomolecular Engineering Metal and bimetallic particles play an important role in catalytic, medical and electronic applications. Various techniques have been developed for the preparation of ...

Pyrolysis of agricultural waste to produce fuel gas involves formation of tars as noxious by-products. In this paper the qualitative analysis of tars formed during pyrolysis of rice husks is presented, based on identification by gas chromatography-mass spectrometry and interpolation of retention times on a polyaromatic hydrocarbon index scale. The influence of some reaction parameters on produc...

Pyrolysis is a relatively simple, inexpensive, and robust thermochemical technology for transforming biomass into bio-oil, biochar, and syngas. The robust nature of the pyrolysis technology, which allows considerable fl exibility in both the type and quality of the biomass feedstock, combined with a distributed network of small pyrolysis plants, would be compatible with existing agriculture and...

The effective management of sewage sludge materials in an environmentally and economically acceptable way is through the pyrolytic conversion of the sludge to biochar and its use for agricultural purposes. The aims of this work were: (1) to assess the effect of biochar prepared from sewage sludge at two different temperatures (350 ºC and 650 ºC) on the adsorption/desorptio...

The major chemical changes during the processing of rubber occur with the breakdown in mastication and during vulcanization of the molded tire. There is little chemical change during the compounding, calendering, extrusion, and molding steps. Reclaiming is the process of converting scrap rubber into an unsaturated, processible product that can be vulcanized with sulfur. Pyrolysis of scrap rubbe...

Pyrolysis mass spectrometry is a rapid and high-resolution method for the analysis of otherwise non-volatile material and has been widely applied for discriminating between closely related microbial strains. Recent advances in statistical and neural network methods based on supervised learning have now permitted exploitation of pyrolysis mass spectrometry in the quantitative analysis of many di...

Matrix isolation IR spectroscopy has been used to study the vacuum pyrolysis of hexamethylcyclotrisiloxane (D3), octamethylcyclotetrasiloxane (D4) and decamethyl cyclopentasiloxane (D5), and the results interpreted in the context of various kinetic models. In particular, it is shown that the significant pyrolysis products--which include CH3, CH4, C2H2, C2H4, C2H6 and SiO--may be satisfactorily ...

Previously, the primary product distribution resulting from fast pyrolysis of cellulose, hemicellulose, and lignin was quantified. This study extends the analysis to the examinations of interactions between cellulose−hemicellulose and cellulose−lignin, which were determined by comparing the pyrolysis products from their native mixture, physical mixture, and superposition of individual component...