Small angle X-ray scattering (SAXS) is an increasingly popular technique for obtaining low resolution solution structures of dynamic macromolecules and complexes. Because SAXS does not require special sample preparation beyond that needed to ensure monodispersity, it is commonly used to probe the dependence of macromolecular conformation or association on different solution conditions (such as ...

Time-resolved in situ SAXS and XAS measurements were carried out to monitor the formation of nanoparticles of the sulfides of cadmium and zinc, from solutions containing he corresponding acetate, and thioacetamide under solvothermal conditions. Analysis of the SAXS data shows that particles of ca 5 nm in radius form within the first few minutes of the reaction and then grow uniformly to ca 20 n...

Small angle X-ray scattering (SAXS) is a potentially powerful method for obtaining structural information from biological molecules in solution. The use of this technique in the laboratory has hitherto been limited by the long exposures necessary to obtain patterns on photographic film. Multi-wire area detectors, due to their high efficiency and absence of noise, enable patterns to be collected...

Two variants of a sample holder were constructed for SAXS (small angle X-ray scattering) and freeze fracture studies of colloid systems during shear stress. The detailed construction of both variants is described. The SAXS investigations give information about the structural changes in the range of nm’s, and the freeze fracture technique makes possible the imaging of the μm-scale morphology. Co...

This paper presents the influence of Hybrane H 1500 as a hyperbranched polymer on kinetic parameters of dyeing compounded fiber grade PET polyethylene terephthalate at boil temperature. C.I. Disperse Red 324 as a disperse dye was used for dyeing compounded fiber grade PET. The result was compared with corresponding properties of virgin PET. The dyeing rate constants and diffusion coefficients a...

This paper describes a system for the study of the relation between structure and applied strain in thermoplastic polyurethane elastomers using the Australian National Beamline Facility at the Photon Factory, KEK, Tsukuba, Japan. The system uses the sagittal focusing monochromator at beamline 20B to provide a high-intensity focused beam which then falls on the specimen mounted in a miniature te...

Small angle x-ray scattering ~SAXS! measurements were performed on nanoporous methyl silsesquioxane films that were generated by the incorporation of a sacrificial polymeric component into the matrix and subsequently removed by thermolysis. The average pore radii ranged from 1 to 5 nm over a porosity range of ;5–50%. The distribution in pore size was relatively broad and increases in breadth wi...

Structural macromolecular parameters of normal and treated (acid & alkali) polyester fibers have been investigated using Small Angle X-ray Scattering (SAXS) technique. Average diameters were calculated from Scanning electron microscope (SEM) micrographs and mechanical parameters were estimated using Instron. Further, crystallinity parameters of the same fibers have been determined using X-ray d...