A 2-D model for the corrosion of spent nuclear fuel inside a failed nuclear waste container has been modified to determine the influence of various redox processes occurring within fractures in the fuel. The corrosion process is driven by reaction of the fuel with the dominant α radiolysis product, H2O2. A number of reactions are shown to moderate or suppress the corrosion rate, including H2O2 ...

In this work, the effects of loading condition and corrosion solution on the corrosion fatigue behavior of smooth steel wire were discussed. The results of polarization curves and weight loss curves showed that the corrosion of steel wire in acid solution was more severe than that in neutral and alkaline solutions. With the extension of immersion time in acid solution, the cathodic reaction of ...

Corrosion tests of 1015 low-carbon steel and two stainless steels (410 and 316L) were conducted in a pure zinc bath (99.98 wt pct Zn) in order to better understand the reaction mechanisms that occur during the degradation of submerged hardware at industrial general (batch) galvanizing operations. Through this testing, it was found that, in general, 316L stainless steel showed the best dissoluti...

One of the heaviest problems of reinforced concrete structures consists in the steel armature corrosion. The steel armature condition affects, above all, the properties of horizontal structures. It is to be noted that the corrosion process itself may not be observable from the outside in many cases. This is why studies of non-destructive methods allowing the researchers to detect the degree of ...

A new coumarin derivative, N,N'-((2E,2'E)-2,2'-(1,4-phenylenebis (methanylylidene))bis(hydrazinecarbonothioyl))bis(2-oxo-2H-chromene-3-carboxamide) PMBH, was synthesized and its chemical structure was elucidated and confirmed using spectroscopic techniques (Infrared spectroscopy IR, Proton nuclear magnetic resonance, 1H-NMR and carbon-13 nuclear magnetic resonance 13C-NMR). The corrosion inhibi...

Linear Polarisation Resistance (LPR) can provide a direct evaluation of the instantaneous rate of corrosion. However it has the disadvantage of requiring a localised breakout of the concrete cover to provide an electrical connection to the steel reinforcement. This paper describes an adaptation of the LPR method and the four-point Wenner resistivity method to give an evaluation of the rate of s...

Corrosion of reinforced concrete (RC) structures has been one of the major causes of structural failure. Early detection of the corrosion process could help limit the location and the extent of necessary repairs or replacement, as well as reduce the cost associated with rehabilitation work. Non-destructive testing (NDT) methods have been found to be useful for in-situ evaluation of steel corros...

2-(1-methyl-4-((E)-(2-methylbenzylidene)amino)-2-phenyl-1H-pyrazol-3(2H)-ylidene)-hydrazineecarbothioamide (HCB) was synthesized as a corrosion inhibitor from the reaction of 4-aminoantipyrine, thiosemicarbazide and 2-methylbenzaldehyde. The corrosion inhibitory effects of HCB on mild steel in 1.0 M HCl were investigated using potentiodynamic polarization (PDP) and electrochemical impedance spe...

The paper presents influence of mechanical surface damage on corrosion resistance of plates made of Cr-Ni-Mo stainless steel, used in funnel chest treatment. The surface of the steel was electrochemically polished and fitted. The surface damage is induced in the given deformation regions and is a potential reason of corrosion. The corrosion tests were realised by recording of anodic polarizatio...

Protective coatings have been deposited on electrogalvanized steel by immersion in solutions containing 2-Butyne-1.4-diol propoxylate (C7H11O3), cerium nitrate, sodium nitrate and sodium sulphate for different immersion periods. The surface morphology and chemical composition of the coatings formed on the electrogalvanized steel were studied using field emission gun scanning electron microscopy...