vanadium supported on highly ordered nanoporous silica (vox-lus-1) was synthesized and characterized by xrd, nitrogen adsorption‑desorption isotherms and uv-visible spectrophotometer. direct oxidation of benzene to phenol in liquid phase by h2o2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). the maximum yield (25%) and selectivity (73%) of the ph...

Efficient photogenerated carrier migration/separation plays a critical role in increasing the photocatalytic performance of g-C3N4. Herein, sulfonic acid group-functionalized g-C3N4 (SACN) was synthesized and then synchronously strengthened by facile-solid-state thermal reaction sulfamic acid. As solid strong acid, can be used to achieve etching on surface with assistance treatment, leading an ...

Mesoporous MCM-41 was coated on Fe3O4 nanoparticles and then functionalized with sulfurochloridic acid to provide a core-shell solid acid nano-catalyst. The catalyst was characterized by transmission electron microscopy (TEM), infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TG), Brunauer-Emmet-Teller analysis (BET) and vibrating sample magnetometery (VSM). The...

The covalent double functionalization of graphene oxide (GO) is an effective approach to tune the properties graphene-like materials. first step ring-opening reaction epoxides by amines, followed second consisting on nucleophilic addition GO hydroxyl groups ?,?-unsaturated carbonyl compound. benefit doubly functionalized possess different functions, confirmed measuring proton conductivity and s...

The surface of mercapto-functionalized mesoporous silica having a highly ordered open pore network was modified into a super-hydrophilic surface through a stepwise sulfonation process involving oxidation and ionization reactions. The initial mesoporous silica was prepared using an acid-catalyzed sol-gel reaction between tetraethoxysilane (TEOS) and 3-mercaptopropyltrimethoxysilane (MPTMS) in th...