The method of matched asymptotic expansions is used to solve for the free surface of a thin liquid drop draining down a vertical wall under gravity. The analysis is based on the smallness of the surface tension term in the lubrication equation. In a region local to the front of the drop, where the surface curvature is large, surface tension forces are significant. Everywhere else, the surface c...

We perform energy estimates for a sharp-interface model of two-dimensional, twophase Darcy flow with surface tension. A proof of well-posedness of the initial value problem follows from these estimates. In general, the time of existence of these solutions will go to zero as the surface tension parameter vanishes. We then make two additional estimates, in the case that a stability condition is s...

It is shown that surface tension effects on the free boundary have a regularizing effect for Hele-Shaw models, which implies existence and uniqueness of classical solutions for general initial domains.

Molecular dynamics simulations have been carried out to investigate the onset of surface condensation. On surfaces with different wettability, we snapshot different condensation modes (no-condensation, dropwise condensation and filmwise condensation) and quantitatively analyze their characteristics by temporal profiles of surface clusters. Two different types of formation of nanoscale droplets ...

We carry out Monte Carlo simulations of physical Lennard-Jones and water clusters and show that the number of physical clusters in vapor is directly related to the virial equation of state. This relation holds at temperatures clearly below the critical temperatures, in other words, as long as the cluster-cluster interactions can be neglected--a typical assumption used in theories of nucleation....

By considering the fact that the surface tension of a real fluid arises from a combination of both repulsive and attractive forces between molecules, a new expression for the interfacial tension has been derived from scaled particle theory (SPT)  based on the work of cavity formation and the interaction energy between molecules. At the critical temperature, the interfacial tension between c...

The effect of the surfactant chain length n on the bending modulus kappa of surfactant monolayers is simulated with a mesoscopic oil-water-surfactant model. We confirm a power law, kappa is proportional to np, as predicted by mean-field theory and found experimentally, and find p approximately 1.5 at a constant surface density and p approximately 1.0 at a constant interfacial tension. This agre...

We study the destabilization mechanism of thin liquid sheets expanding in air and show that dilute oil-in-water emulsion-based sheets disintegrate through the nucleation and growth of holes that perforate the sheet. The velocity and thickness fields of the sheet outside the holes are not perturbed by holes, and hole opening follows the Taylor-Culick law. We find that a prehole, which widens and...