tetra-n-butyl ammonium hydroxide was used as a catalyst for one-pot, three component condensation reactions consisting of aromatic aldehydes, malononitrile and barbituric acid in ethanol:water solvent system at 60oc. current method has major advantages like mild reaction conditions with simple operation, high yields, by using a less toxic and lower costlier catalyst.in conclusion, we have explo...

Tetra-N-Butyl Ammonium Hydroxide was used as a catalyst for one-pot, three component condensation reactions consisting of aromatic aldehydes, malononitrile and barbituric acid in ethanol:water solvent system at 60oC. Current method has major advantages like mild reaction conditions with simple operation, high yields, by using a less toxic and lower costlier catalyst.In conclusion, we have explo...

In the asymmetric unit of title coordination polymer, {(C(16)H(36)N)[Zn(3)(C(9)H(3)O(6))(2)(OH)]·0.25H(2)O}(n), there are three independent Zn(2+) cations, two benzene-1,3,5-tricarboxyl-ate ligands and a μ(3)-bridging hydroxide group, together with a tetra-n-butyl-ammonium counter-cation and a partially occupied water molecule of solvation (occupancy 0.25). Each Zn ion is coordinated by three c...

In the crystal structure of the title salt, C16H36N(+)·CH3BN(-), the tetra-n-butyl-ammonium cations and [BH3(CN)](-) anions are connected via weak C-H⋯N inter-actions, forming chains along the b-axis direction. The anion is almost linear with an N-C-B angle of 178.7 (2)°. The C-N-C angle values at the core of the tetra-n-butyl-ammonium cation range from 105.74 (11) to 111.35 (11)° with an avera...

cis-polybutadiene was functionalized using in–situ generated dmd as oxidant and tetra-n-butyl ammonium bromide as phase transfer catalyst (ptc). the epoxidation process was investigated by 1hnmr spectroscopy. 1hnmr spectrum analysis of products confirms the absence of ring opening side products in epoxidation reaction. various factors such as reaction temperature, reaction time and the concentr...

The title compound, C(4)H(12)N(+)·C(8)H(11)NO(5)PS(-), was obtained from tetra-methyl-ammonium hydroxide and dimeth-yl(phenyl-sulfon-yl)amido-phosphate. The tetra-methyl-ammonium cation has a slightly distorted tetra-hedral configuration and the N-C bond lengths lie in the range 1.457 (3)-1.492 (3) Å. In the crystal, no classical hydrogen bonds are observed between the cation and the anion.

The title compounds, tetra-butyl-ammonium chloride-1,1'-(1,2-phenyl-ene)bis-(3-m-tolyl-urea) (1/1), C16H36N+·Cl-·C22H22N4O2 or [(n-Bu4N+·Cl-)(C22H22N4O2)] (I) and tetra-butyl-ammonium bromide-1,1'-(1,2-phenyl-ene)bis-(3-m-tolyl-urea) (1/1), C16H36N+·Br-·C22H22N4O2 or [(n-Bu4N+·Br-)(C22H22N4O2)] (II), both comprise a tetra-butyl-ammonium cation, a halide anion and an ortho-phenyl-ene bis-urea mo...

In the title compound, (C(16)H(36)N)[Fe(C(12)H(8)N(3)O(2))(CN)(3)]·2H(2)O, the tetra-n-butyl-ammonium ion has a tetra-hedral configuration around the N atom, while the Fe(III) atom of the tricyanido[N-(2-pyridyl-carbon-yl)pyridine-2-carboximidato]iron(III) anion adopts a distorted octa-hedral geometry. O-H⋯O and O-H⋯N hydrogen bonds link the components in the crystal structure.