titanium (ti) is a relatively abundant element that has found growing applications in medical science and recently some of ti compounds are introduced as anticancer drugs. in spite of very limited data which exist on the ti metabolism, some proteins might be involved in the mechanism of action of ti. up to our knowledge, there is not any report in the literature concerning binding of ti to apol...

NaCl­KCl­TiClx was prepared via using titanium sponge to reduce titanium tetrachloride in a NaCl­KCl melt under a negative pressure at 1023K. The relationship between titanium valence states and [F]/[Ti] molar ratios was investigated with successive adding potassium fluoride in the pre-prepared NaCl­KCl­TiClx. It was found that the average valence of titanium ions tended to be stable around 3.0...

We have proposed a combination of density functional theory calculations and interatomic potential-based simulations to study the structural, electronic, and mechanical properties of pure-silica zeolite Linde Type A (LTA), as well as two titanium-doped compositions. The energetics of the titanium distribution within the zeolite framework suggest that the inclusion of a second titanium atom with...

The mechanical properties of titanium Grade 2 subjected to the hydrostatic extrusion technique (HE) were investigated. The hydrostatic extrusion technique is a method which refines the titanium grains to a nano-metric size. Compared with coarse grained titanium (CG-Ti), nanocrystalline titanium (NC-Ti) is characterized by a much higher yield stress, tensile strength and microhardness. The yield...

ti-mcm-41 was synthesized at ph 3, 7 and 11. the titanium content was determined by aas and found to be 4%, 3.2% and 4.5%, respectively. in order to increase the titanium content in ti-mcm-41, ti(iv) ions were grafted onto ti-mcm-41 using ticl4 in toluene and ti(obu)4 in ethanol. the incorporation of ti was determined to be 28% and 30%, respectively. the oxidation of olefins such as cyclopenten...

Titanium and titanium alloy are widely used as orthopedic implants for their favorable mechanical properties and satisfactory biocompatibility. The aim of the present study was to investigate the antibacterial effect and bone cell biocompatibility of a novel implant made with nanotubular anodized titanium coated with gentamicin (NTATi-G) through in vivo study in rabbits. The animals were divide...

Reaction products of titanium(IV) sulfate in HCl-acidic aqueous solution with the dimeric species linked through three intermolecular Ti-O-Ti bonds of the two trititanium(IV)-substituted α-Keggin polyoxometalate (POM) subunits are described. Two novel titanium(IV)-containing α-Keggin POMs were obtained under different conditions. One product was a dimeric species through two intermolecular Ti-O...

At the beginning of the present century it has been demonstrated that nanocrystalline titanium (NC-Ti) can be fabricated by hydrostatic extrusion (HE) which is one of the severe plastic deformation method. NC-Ti obtained in such a way exhibited excellent mechanical properties. The influence of HE on the microstructure and mechanical properties of titanium Grade 2 was first analyzed in 2005. In ...

Porous titanium carbide (TiC) and TiC/Ti composites were synthesized by self-propagating high-temperature synthesis (SHS). Titanium and carbon powders were blended by various Ti/C blending ratios. The heat of reaction between titanium and carbon was high enough to induce the self-sustaining reaction of TiC formation on condition that some processing parameters (Ti/C ratio and porosity of the pr...

Surface modification of titanium implants is used to enhance osseointegration. The study objective was to evaluate five modified titanium surfaces in terms of cytocompatibility and pro-osteogenic/pro-angiogenic properties for human mesenchymal stromal cells: amorphous microporous silica (AMS), bone morphogenetic protein-2 immobilized on AMS (AMS + BMP), bio-active glass (BAG) and two titanium c...