support vector regression (svr) is a learning method based on the support vector machine (svm) that can be used for curve fitting and function estimation. in this paper, the ability of the nu-svr to predict the catalytic activity of the fischer-tropsch (ft) reaction is evaluated and the result is compared with two other prediction techniques including: multilayer perceptron (mlp) and subtractiv...

Microkinetics simulations are presented based on DFT-determined elementary reaction steps of the Fischer-Tropsch (FT) reaction. The formation of long-chain hydrocarbons occurs on stepped Ru surfaces with CH as the inserting monomer, whereas planar Ru only produces methane because of slow CO activation. By varying the metal-carbon and metal-oxygen interaction energy, three reactivity regimes are...

Fischer–Tropsch technology has gathered renewed interest in the energy industry in recent times for synthesis of diesel and gasoline. The synthesis of linear hydrocarbon diesel fuel (having high cetane number) through Fischer–Tropsch synthesis (FTS) reaction requires syngas with high H2/CO molar ratio. Producer gas obtained from biomass gasification has low H2/CO ratios, with significant conten...

Fischer-Tropsch(FT) reaction involves the hydrogenation of carbon monoxide to hydrocarbons typically by group VIII metals [1]. Cobalt is one of the first metals used as FT catalyst and is typically mixed with Mn to promote carbon monoxide conversion to more valuable higher (C5+) hydrocarbons and olefins. The properties of metal catalysts can be controlled by fine-tuning chemical composition, su...

The Fischer–Tropsch process is a collection of chemical reactions that converts mixture carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These occur in the presence metal catalysts, typically at temperatures 150–300°C (302–572°F) pressures one to several tens atmospheres. an important reaction both coal liquefaction gas liquids technology for producing In usual implement...

There is a world-wide demand for clean, reliable and affordable energy. New technologies are needed to produce more oil and natural gas from ‘stranded’ locations. This work is based on gas to liquid (GTL) conversion of natural gas through Fischer-Tropsch (FT) synthesis. Fe & Co based catalysts of varying compositions were prepared in the laboratory and its performance was checked for the FT rea...

The control on product distributions in Fischer-Tropsch synthesis by feeding olefins in the n-paraffin solvent over a 20 wt.% Co/SiO2 catalyst under the typical reaction conditions of 503K, 2.1MPa, H2/CO = 2, and co-fed olefins 16 mol% in CO base in a trickle bed reactor has been studied. The selected co-fed olefins include 1-octene, 2-octene and 1-dodecene. Results showed that the addition of ...

The design and optimization of a natural gas to hydrocarbon liquids (GTL) process is considered, mainly from the view of maximizing the variable income during operation. Autothermal reforming (ATR) is used for synthesis gas production. The kinetic model for Fischer Tropsch (FT) reactions is the one given by Iglesia et al. for a cobalt-based FT reactor. For the product distribution, three altern...

The Fischer-Tropsch synthesis (FTS) has been recognized as a heterogeneous surface-catalyzed polymerization process. During this process, CHx monomers formed via the hydrogenation of adsorbed CO on transition metals produce hydrocarbons and oxygenates with a broad range of chain lengths and functional groups. A series of Fe/Cu Fischer-Tropsch synthesis catalysts incorporated with a calcium prom...

In this paper we present the conceptual design for the optimization of FT-diesel production process from switchgrass via gasification of biomass. We propose a limited superstructure where the process starts with the gasification of the biomass. Two different alternatives are evaluated, direct and indirect gasification. The gas obtained is cleaned up and its composition adjusted in terms of the ...