A selective electrochemical method for the determination of uric acid was developed by using nano poly cresol red modified glassy carbon electrode. This new material has been characterized by Scanning Electron Microscopy, cyclic voltammetry and Differential pulse voltammetry. This modified electrode shows excellent electrocatalytic activity towards the oxidation of uric acid in the presence of ...

Theory is presented for cyclic voltammetry at a hemispherical electrode under conditions where the electric field is nonzero and migration is significant to mass transport. The nonlinear set of differential equations formed by combining the Nernst-Planck equation and the Poisson equation are solved numerically, subject to a zero-field approximation at the electrode surface. The effects on the o...

A novel gold nanoparticle-modified graphite pencil electrode (AuNP-GPE) is prepared just by immersing a bare GPE in AuNP solution, followed by heating for 15 min. The bare and modified GPEs are characterized by FE-SEM imaging and cyclic voltammetry. The AuNP-GPEs showed excellent electrocatalytic activities with respect to hydrazine oxidation, with good reproducibility. To reduce the quantifica...

The electrochemical behaviour of L-cysteic acid was studied at the surface of 1-[4-(ferrocenylethynyl)phenyl]-1-ethanone modified carbon paste electrode (4FEPEMCPE) in aqueous media using cyclic voltammetry and double step potential chronoamperometry. It has been found, that under optimum condition (pH 7.00) in cyclic voltammetry, the oxidation of L-cysteic acid at the surface of 4FEPEMCPE is o...

This paper deals with the development of an electrochemical sensor base on Trypan Blue (TB) towards the determination of Dopamine (DA). An electrochemical sensor was fabricated by the electropolymerization of TB onto the Carbon paste electrode (CPE) using cyclic voltammetry (CV) technique. The polymerized TB modified CPE (Poly(TB)MCPE) was characterized using Electrochemical impedance spectrosc...

Thermal modulation (TM) voltammetry was successfully applied to the determination of phosphate ion in natural water, by using a He-Cd dual laser as a heating source and a graphite-reinforced carbon (GRC) electrode. A heteropoly ion, i.e., 12-molybdophosphate ion ([PMo(VI)(12)O(40)](3-)), was formed through a reaction between a phosphate ion and molybdate ions in an acidic solution, and its elec...

A simple and sensitive electrochemical sensor for detection of dopamine has been developed based on ionic liquid functionalized graphene oxide supported gold nanoparticles (GO-IL-AuNPs) coated onto a glassy carbon electrode. The prepared graphene oxide, ionic liquid functionalized graphene oxide and GO-IL-AuNPs were characterized in detail by scanning electron microscopy, X-ray diffraction and ...

The transfer of polyammonium ions, poly[(dimethylimino)-1,6-hexanediyl] (n = 140, n being the degree of polymerization) ion and poly[(dimethylimino)(2-oxo-1,2-ethanediyl)imino-alpha,omega-alkanediylimino(1-oxo-1,2-ethanediyl)(dimethylimino)-alpha',omega'-alkanediyl] ([-N+ (CH3)2CH2CONH(CH2)x NHCOCH2N+ (CH3)2(CH2)y-]n, x = 2, 3, 4, or 6, y = 3 or 6, and n = 30-130) ions, at a polarizable nitrobe...

The electrocatalytic oxidation of captopril (CAP) was studied by modified carbon nanotubes paste electrode in the presence of isoproterenol (ISPT) using cyclic voltammetry (CV), chronoamperometry and square wave voltammetry (SWV). Also, the values of catalytic rate constant (k), and electron transfer coefficient (α) for CAP were calculated. The mechanism of CA electrochemical behavior at the mo...