نتایج جستجو برای: wc 10co 4cr
تعداد نتایج: 6494 فیلتر نتایج به سال:
By combining an Ugi-4CR and a gold-catalyzed cascade cyclization, diverse benzazepinoindoles are assembled in step-economical, chemo- regioselectivity fashion.
A metal-free chemodifferentiating A2BB' 4CR manifold for the modular synthesis of tertiary skipped diynes is described. The manifold performs a triethylamine triggered reaction of alkyl propiolates and acid chlorides to assemble two units of each component in the form of two propargylic alkynoates, a tertiary alcohol, and an ester. A differentiated incorporation of the two acid chloride compone...
A library of ten 1,3-diyne-linked peptoids has been synthesized through an Ugi four-component reaction (U-4CR) followed by a copper-catalysed alkyne homocoupling (Glaser reaction). The short and chemoselective reaction sequence allows generating diverse (pseudo) dimeric peptoids. A combinatorial version allows the one-pot preparation of, e.g., six-compound-libraries of homo- and heterodimers ve...
A practical, integrated and versatile U-4CR-based assembly of 1,4-benzodiazepin-2-ones exhibiting functionally, skeletally, and stereochemically diverse substitution patterns is described. By virtue of its convergence, atom economy, and bond-forming efficiency, the methodology documented herein exemplifies the reconciliation of structural complexity and experimental simplicity in the context of...
A novel selectively sequential C-S/C-N bond activation is presented. Through the combination of an Ugi-4CR and cleavage, diverse peptidomimetics containing a primary amide are prepared in a...
The effect of post-irradiation annealing on the microstructures and mechanical properties of V-4Cr-4Ti alloys was studied. Helium-hydrogen-irradiated sequentially V-4Cr-4Ti alloys at room temperature (RT) were undergone post-irradiation annealing at 450 °C over periods of up to 30 h. These samples were carried out by high-resolution transmission electron microscopy (HRTEM) observation and nanoi...
Passerini (P-3CR) and Ugi (U-4CR) reactions were investigated in 4-oxoazetidine-2-carboxaldehydes, affording the corresponding Passerini and Ugi adducts with moderate diastereoselectivity in high yields. Fortunately, the obtained mixtures of isomers syn/anti were separated in most cases. The scope of both IMCRs has been studied using a variety of isocyanides, carboxylic acids and amines. Ugi ad...
مواد تنگستن مونوکارباید-کبالت نانوساختار تفت¬جوشی شده به دلیل داشتن تلفیقی از سختی و چقرمگی بالا به عنوان گزینه¬ی مناسبی برای گستره¬ی وسیعی از کاربردهای مقاوم به سایش نظیر ابزارهای برش¬کاری و سوراخ¬کاری و ساخت قالب¬های اکستروژن استفاده می¬شوند. اما بکارگیری ذرات تنگستن مونوکارباید-کبالت نانوساختار جهت تولید پوشش¬های نانوساختار بوسیله¬ی فرایند پاشش شعله¬ای پرسرعت، منجر به افت مقاومت سایشی در مقا...
This study investigates the effect of carbide particle size on the microstructure, mechanical properties, and abrasive wear resistance of WC-17%Co HVOF-sprayed coatings. The characteristics of WC-1, WC-2, and WC-3 coatings with carbide sizes of 1 µm, 0.9 µm, and 0.5 µm, respectively, were also investigated. WC-1 coating experienced the maximum carbon loss of 42%, while WC-2 and WC-3 coatings un...
In the frq-wc-based circadian feedback loops of Neurospora, two PAS domain-containing transcription factors, WHITE COLLAR-1 (WC-1) and WC-2, form heterodimeric complexes that activate the transcription of frequency (frq). FRQ serves two roles in these feedback loops: repressing its own transcription by interacting with the WC complex and positively upregulating the levels of WC-1 and WC-2 prote...
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