In the present study, a laboratory scale corn-cob based biofilter inoculated with pseudomonas fluorescents (mtcc 9768) was used for investigating the degradation of ethylbenzene and m-xylene for a period of 60 days in two phases. for ethylbenzene maximum removal efficiency (re) was 72% at an inlet concentration of 4.26 gm -3 and for m-xylene re was 76% at an inlet concentration of 6.39 g m -3 a...

This paper reports the electrochemical behavior of lactate dehydrogenase (LDH) immobilized in the silica sol-gel film on gold electrode after adding nanometre-sized tridecameric aluminium polycation (nano-Al13, also called nanopolynuclear Al13) as a promoter. A pair of surface controlled quasi-reversible cyclic voltammetry peaks with the formal potential (E0') of 154 mV (vs. SCE) was found in t...

Photoluminescence of |22|Paracyclophane and p-Xylene in the Presence of Silver Ions M. Zander Laboratory of Rütgerswerke AG, Castrop-Rauxel Z. Naturforsch. 39a, 10091010 (1984); received August 18. 1984 Phosphorescence spectra and phosphorescence lifetimes of [22]paracyclophane (I) and p-xylene have been mea­ sured in ethanol glass at 77 K in the presence of silver Perchlorate at various concen...

T hree solutions for removing the dangerous volatile organic compound (VOC) xylene from an industrial coating process are presented and compared. Two of them are based on classical process engineering principles, i.e., development of separationcleaning methods such as incineration and adsorption. The last approach is somewhat different and is based on the so-called product engineering concept, ...

Protein detection methods in formalin-fixed paraffin embedded (FFPE) tissue blocks are widely used in research and clinical setting in order to diagnose or to confirm a diagnosis of various types of diseases. Therefore, multiple protein extraction methods from FFPE tissue sections have been developed in this regard. However, the yield and the quality of proteins extracted from FFPE tissues are ...

This computational and theoretical study deals with chain transfer to solvent (CTS) reactions of methyl acrylate (MA), ethyl acrylate (EA), and n-butyl acrylate (n-BA) self-initiated homopolymerization in solvents such as butanol (polar, protic), methyl ethyl ketone (MEK) (polar, aprotic), and p-xylene (nonpolar). The results indicate that abstraction of a hydrogen atom from the methylene group...

Toluene and xylene are aromatic hydrocarbons commonly used as an industrial solvent for the manufacturing of pharmaceuticals, paints, and chemicals. The Occupational Safety and Health Administration has determined that toluene levels of 2000 parts per million (ppm) are considered dangerous to life and health. Several studies have examined the absorption of toluene and xylene following inhalatio...

Renewable production of p-xylene from [4 + 2] Diels− Alder cycloaddition of 2,5-dimethylfuran (DMF) and ethylene with H−Y zeolite catalyst in n-heptane solvent is investigated. Experimental studies varying the solid acid catalyst concentration reveal two kinetic regimes for the p-xylene production rate: (i) a linear regime at low acid site concentrations with activation energy Ea = 10.8 kcal/mo...

The primary objective of this study was to evaluate the impact of substrate interactions on the biotransformation rates and mineralization potentials of gasoline monoaromatics and methyl tert-butyl ether (MTBE), compounds that commonly co-exist in groundwater contaminant plumes. A mixed culture was derived from gasoline-contaminated aquifer material using toluene as the enrichment substrate. Tw...

Enrichment cultures obtained from soil exposed to benzene, toluene, and xylene (BTX) mineralized benzene and toluene but cometabolized only xylene isomers, forming polymeric residues. This observation prompted us to investigate the metabolism of 14C-labeled BTX hydrocarbons in soil, either individually or as mixtures. BTX-supplemented soil was incubated aerobically for up to 4 weeks in a sealed...