[6-(Hydroxymethyl)pyridin-2-yl]methyl ferrocene-1-carboxylate
نویسندگان
چکیده
منابع مشابه
[6-(Hydroxymethyl)pyridin-2-yl]methyl ferrocene-1-carboxylate
The crystal structure of the title ferrocene derivative, [Fe(C(5)H(5))(C(13)H(12)NO(3))], shows strong inter-molecular O-H⋯N hydrogen bonds between the alcohol function and the pyridine group of a neighbouring mol-ecule, while the pyridine function forms another hydrogen bond with the alcohol function of another neighbouring mol-ecule, resulting in the formation of chains along the a-axis direc...
متن کاملSynthesis and Structure of Geometric Isomers of 1-[(methoxyimino)ethyl]- ferrocene and Methyl 1'-[(methoxyimino)ethyl]ferrocene-1-carboxylate
Here we report synthesis, spectral data and single-crystal X-ray molecular and crystal structures of (E)-1-[(methoxyimino)ethyl] ferrocene (2) and (E)-methyl 1'-[(methoxyimino)ethyl]ferrocene-1carboxylate (4). These organometallics are recognized as precursors for optically pure (1ferrocenylethyl)amine (Fea) and 1'-(1-aminoethyl)ferrocene-1-carboxylic acid (Fcca) derivatives. The (E/Z)mixtures...
متن کاملCrystal and Molecular Structure Studies of Ethyl 4-(4-Hydroxyphenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate and Ethyl 4-(3-Bromophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate
The crystal and molecular structures of the title compounds, ethyl 4-(4-hydroxyphenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate (I) and ethyl 4-(3-bromophenyl)-6-(6-methoxy-2-naphthyl)-2-oxocyclohex-3-ene-1-carboxylate (II), are reported and confirmed by single crystal X-ray diffraction data. Compound (I), C26H24O5, crystallizes from a methanol solution in the monoclinic C2/c ...
متن کامل[(E)-1-(Naphthalen-2-yl)ethylidene](naphthalen-1-ylmethyl)amine
The title compound, C(23)H(19)N, was obtained unexpectedly from the reaction of [Eu(nta)(3)(PzPy)] {Hnta = 1-(2-naphtho-yl)-3,3,3-trifluoro-acetone and PzPy = 2-[3(5)-pyrazol-yl]pyridine} with 1-naphthyl-methyl-amine. The 1- and 2-naphthyl groups are essentially planar [r.m.s. deviations of 0.007 and 0.011 Å, respectively] and subtend angles of 38.69 (11) and 16.50 (11)°, respectively, with the...
متن کاملMethyl 3-(2-chlorophenyl)-2-(1H-indol-3-ylmethyl)-5-[1-(4-methoxyphenyl)-4-oxo-3-phenylazetidin-2-yl]-4-nitropyrrolidine-2-carboxylate
In the mol-ecule of the title compound, C(37)H(33)ClN(4)O(6), the four-membered β-lactam ring is essentially planar and is oriented at dihedral angles of 30.0 (1), 76.3 (1) and 30.9 (1)° with respect to the methoxy-phenyl ring, the phenyl ring and the indole unit, respectively. The pyrrolidine ring adopts a twist conformation. Intra-molecular C-H⋯Cl and C-H⋯O hydrogen bonds result in the format...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811043972