A Deeper Understanding of Metal Nucleation and Growth in Rechargeable Metal Batteries Through Theory and Experiment

Lithium and sodium metal batteries continue to occupy the forefront of battery research. Their exceptionally high energy density nominal voltages are highly attractive for cutting‐edge storage applications. Anode‐free also coming into research spotlight offering improved safety even higher densities than conventional batteries. However, uneven nucleation growth which leads dendrites continues limit commercialisation anode‐free alike. This review connects models theories from well‐established fields in metallurgy electrodeposition both These applicable explain driving forces can inform future experiment design. Finally, that most relevant each anode‐related cell component identified. Keeping these specific mind will assist with rational design components.