A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites
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A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites.
Oxygen-oxygen bond formation and O2 generation occur from the S4 state of the oxygen-evolving complex (OEC). Several mechanistic possibilities have been proposed for water oxidation, depending on the formal oxidation state of the Mn atoms. All fall under two general classifications: the AB mechanism in which nucleophilic oxygen (base, B) attacks electrophilic oxygen (acid, A) of the Mn4Ca clust...
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ژورنال
عنوان ژورنال: Philosophical Transactions of the Royal Society B: Biological Sciences
سال: 2007
ISSN: 0962-8436,1471-2970
DOI: 10.1098/rstb.2007.2226