A Small Paramagnetic Platinum Cluster in an NaY Zeolite: Characterization and Hydrogen Adsorption and Desorption
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چکیده
منابع مشابه
A small paramagnetic platinum cluster in an NaY zeolite: characterization and hydrogen adsorption and desorption.
A well-defined cluster containing 12 equivalent platinum atoms was prepared by ion exchange of an NaY zeolite, followed by hydrogen reduction. It was characterized by electron paramagnetic resonance (EPR) spectroscopy, hyperfine sublevel correlation (HYSCORE), and theoretical calculations. Combing the results of the experiments with density functional calculations, the likely structure of this ...
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Hydrogen production from biomass has been paid more attention for years. Processes suggested for production of hydrogen from biomass are often involved in high-temperature pyrolysis, catalytic steam reforming or enzymatic biosynthesis. These strategies, however, encounter problems of high consumption of energy, low catalyst efficiency and very limited productivity. Group VIII metals such as Pt,...
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The surfaces of NaY zeolite particles were modified by the alkylsilylation of n-octadecyltrichlorosilane (OTS). Two kinds of modified NaY zeolites were prepared; one with its external surface partially and the other fully covered with alkylsilyl groups. Since the size of OTS is bigger than the pore diameter of NaY, it is attached on the external surface, leaving the internal pore accessible to ...
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A bimetallic precursor route toward the encapsulation of subnanometer tin-transition metal alloy clusters in zeolites is presented. The intrazeolite chemistry and thermal stability of MesSnCo(CO)4 in NaY zeolite were studied with X-ray absorption spectroscopy (Sn, Co edge EXAFS) and in-situ FTIR/TPD-MS techniques. In the NaY host, the intact precursor is physically adsorbed from hexane solution...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry B
سال: 2006
ISSN: 1520-6106,1520-5207
DOI: 10.1021/jp0561874