An Epoxy Adhesive Crosslinked through Radical?Induced Cationic Frontal Polymerization

Cationic polymerization of glycidyl ethers and furans: improved electron beam and UV cured epoxy networks

Modelling Cyclic Moisture Uptake in an Epoxy Adhesive

This paper presents a methodology for predicting moisture concentration in an epoxy adhesive under cyclic moisture absorption-desorption conditions. The diffusion characteristics of the adhesive were determined by gravimetric experiments under cyclic moisture conditions and the dependence of diffusion coefficient and saturated mass uptake on moisture history was determined. Non-Fickian moisture...

Predicting Mechanical Response of Crosslinked Epoxy using ReaxFF

The development of improved epoxy resins can be greatly facilitated using molecular dynamics (MD) techniques. Because molecular-level failure events can play a significant role in epoxy mechanical behavior, the reactive force field (ReaxFF) is an ideal tool for MD simulations of crosslinked epoxies. The results of this study demonstrate that mechanical stiffness and strength values predicted wi...

Computing thermomechanical properties of crosslinked epoxy by molecular dynamic simulations

This paper reports the use of molecular dynamics simulations to study the thermomechanical properties of an epoxy molding compound formed by curing tri/tetra-functionalized EPN1180 with Bisphenol-A. An interactive crosslinking-relaxation methodology is developed to construct the simulation cell. This crosslinking-relaxation methodology allows the construction of highly crosslinked polymer netwo...

Wavelength tunability in photoinitiated cationic polymerization

Onium salts, widely used cationic photoinitiators, have absorption in the short wavelength of the UV spectrum. However, their spectral sensitivity can be tuned up to the visible region by using several methods. Photosensitization of onium salts, their charge transfer complex formation and their free radical promotion are some techniques that are used to provide wavelength flexibility. This chap...