Analysis of effective surface area for electrochemical reaction derived from mass transport property
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When one incorporates transport effects into a surface-volume reaction, an integrodifferential equation for the bound state concentration occurs. Such a form is inconvenient for data analysis. An effective rate constant approximation for the solution is correct to 0(Da2) as the Damkohler number Da ---) 0. A numerical simulation of the integrodifferential equation is performed which shows that t...
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ژورنال
عنوان ژورنال: Journal of Electroanalytical Chemistry
سال: 2014
ISSN: 1572-6657
DOI: 10.1016/j.jelechem.2014.09.023