Approaches to Suppress CO2-Induced Plasticization of Polyimide Membranes in Gas Separation Applications
نویسندگان
چکیده
منابع مشابه
Plasticization of gas separation membranes*
For the investigation of the plasticizing effect of carbon dioxide on polymers used for gas separation membranes new experimental methods have been developed that measure the sorption kinetics as well as the dilation kinetics. Comparing dilation and sorption kinetics at low and elevated pressures gives information about different types of swelling behaviour depending on the pressure level. Volu...
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In this work, three different graphene-based materials, namely graphite oxide (GrO), thermally reduced graphite oxide (T-RGrO) and ascorbic acid multi-phase reduced graphene oxide (AMP-RGO), were synthesized and used to produce mixed matrix membranes (MMM) based on Matrimid®5218 for as separation. From the samples produced, a complete set of characterization was performed including XRD, FTIR, T...
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Matrimid®5218 hollow fiber membranes were prepared using the dry-wet spinning process. The transport properties were measured with pure gases (H2, CO2, N2, CH4 and O2) and with a mixture (30% CO2 and 70% N2) in dry and wet conditions at 25 °C, 50 °C, 60 °C and 75 °C and up to 600 kPa. Interesting values of single gas selectivity up to 60 °C (between 31 and 28 for CO2/N2 and between 33 and 30 fo...
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Poly (ether-block-amide) /poly (ethylene glycol)/ carbon nanotubes mixed matrix membranes have been successfully fabricated using solvent evaporation method to determine the effect of ethylene oxide groups on the performance of produced membranes. The effects of CNTs (2-8 wt%) and PEG (up to 50 wt%)were investigated in both single and mixed gas test setup in different temperature and pressure. ...
متن کاملSynthesis of PIL membranes for CO2 separation
Carbon dioxide (CO2) can be commonly found in natural gas streams, biogas, flue gas and product of coal gasification[1]. The presence of CO2 and other acid gases reduce the thermal efficiency and make the gas streams become acidic and corrosive, which in turn reduces the possibilities of gas compression and the transport within the transportation systems[2]. Membrane separation is a promising t...
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ژورنال
عنوان ژورنال: Processes
سال: 2019
ISSN: 2227-9717
DOI: 10.3390/pr7010051