Architectured Interfaces and Electrochemical Modelling in an Anode Supported SOFC

Ambient Pressure XPS Study of Mixed Conducting Perovskite-Type SOFC Cathode and Anode Materials under Well-Defined Electrochemical Polarization

The oxygen exchange activity of mixed conducting oxide surfaces has been widely investigated, but a detailed understanding of the corresponding reaction mechanisms and the rate-limiting steps is largely still missing. Combined in situ investigation of electrochemically polarized model electrode surfaces under realistic temperature and pressure conditions by near-ambient pressure (NAP) XPS and i...

Optimization of the Interconnect Ribs for a Cathode-Supported Solid Oxide Fuel Cell

A comprehensive mathematical model of the performance of the cathode-supported solid oxide fuel cell (SOFC) with syngas fuel is presented. The model couples the intricate interdependency between the ionic conduction, electronic conduction, gas transport, the electrochemical reaction processes in the functional layers and on the electrode/electrolyte interfaces, methane steam reforming (MSR) and...

An Examination of SOFC Anode Functional Layers Based on Ceria in YSZ

The properties of solid oxide fuel cell (SOFC) anode functional layers prepared by impregnation of ceria and catalytic metals into porous yttria-stabilized zirconia (YSZ) have been examined for operation at 973 K. By varying the thickness of the functional layer, the conductivity of the ceria-YSZ composite was determined to be only 0.015–0.02 S/cm. The initial performance of anodes made with ce...

Numerical Study of Heterogeneous Reactions in an SOFC Anode with Oxygen Addition

Previous experimental studies have shown that addition of small amounts of oxygen to a hydrocarbon fuel stream can control coking in the anode, while relatively large amounts of oxygen are present in the fuel stream in single-chamber solid oxide fuel cells SOFCs . In order to rationally design an anode for such use, it is important to understand the coupled catalytic oxidation/ reforming chemis...

Electrochemical Impedance Spectroscopy Study of the Mass Transfer in an Anode-Supported Microtubular Solid Oxide Fuel Cell