Are Fluorination and Chlorination of Morpholinium-Based Ionic Liquids Favorable?

Glycoside-Based Ionic Liquids

Regioselective chlorination and bromination of unprotected anilines under mild conditions using copper halides in ionic liquids

By using ionic liquids as solvents, the chlorination or bromination of unprotected anilines at the para-position can be achieved in high yields with copper halides under mild conditions, without the need for potentially hazardous operations such as supplementing oxygen or gaseous HCl.

Fluorination effects on the thermodynamic, thermophysical and surface properties of ionic liquids.

This paper reports the thermal, thermodynamic, thermophysical and surface properties of eight ionic liquids with fluorinated alkyl side chain lengths equal or greater than four carbon atoms. Melting and decomposition temperatures were determined together with experimental densities, surface tensions, refractive indices, dynamic viscosities and ionic conductivities in a temperature interval rang...

Catalytic dehydrative etherification and chlorination of benzyl alcohols in ionic liquids.

Dibenzyl ethers and benzyl chloride can be obtained in moderate to excellent yields through Pd-catalysed reactions in hydrophobic ionic liquids using microwave or conventional heating.

Triazolium-based energetic ionic liquids.

The energetic ionic liquids formed by the 1,2,4-triazolium cation family and dinitramide anion are investigated by ab initio quantum chemistry calculations, to address the following questions: How does substitution at the triazolium ring's nitrogen atoms affect its heat of formation, and its charge delocalization? What kind of ion dimer structures might exist? And, do deprotonation reactions oc...