Asymmeric Formal [3 + 3]-Cycloaddition Reactions of Nitrones with Electrophilic Vinylcarbene Intermediates
نویسندگان
چکیده
منابع مشابه
1,3-Dipolar [3 + 2] cycloaddition reactions of N,C,C-trisubstituted nitrones with ring-acceptor methylenecyclopropanes: a computational study
BACKGROUND 1,3-Dipolar [3 + 2]-cycloaddition of nitrones to the carbon-carbon double bonds of methylenecyclopropanes yields a mixture of regioisomeric 4- and 5-isoxazolidines. The mechanisms of the reactions of N,C,C-trisubstituted nitrones with ring acceptor substituted dimethyl methylenecyclopropanes-1,2-dicarboxylate and aryl methylidene cyclopropanes-1,1-dicarboxylate have been investigated...
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Azaoxyallyl cations represent a family of versatile and powerful synthetic synthons, which are generally in situ generated from a-halohydroxamates in the presence of organic or inorganic bases. Owing to the unique structural features and reactivities of azaoxyallyl cations, some various efforts have been made to enrich the synthetic methodology of azaoxyallyl cations (Scheme 1, 1). In 2011, Jef...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2011
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja207664r