Bicyclic naphthenic acids in oil sands process water: Identification by comprehensive multidimensional gas chromatography–mass spectrometry

Bicyclic naphthenic acids in oil sands process

Naphthenic Acids in Athabasca Oil Sands Tailings Waters Are Less Biodegradable than Commercial Naphthenic Acids

Naphthenic acids (NAs) are natural constituents in many petroleum sources, including bitumen in the oil sands of Northern Alberta, Canada. Bitumen extraction processes produce tailings waters that cannot be discharged to the environment because NAs are acutely toxic to aquatic species. However, aerobic biodegradation reduces the toxic character of NAs. In this study, four commercial NAs and the...

Naphthenic acids in athabasca oil sands tailings waters are less biodegradable than commercial naphthenic acids.

Naphthenic acids (NAs) are natural constituents in many petroleum sources, including bitumen in the oil sands of Northern Alberta, Canada. Bitumen extraction processes produce tailings waters that cannot be discharged to the environment because NAs are acutely toxic to aquatic species. However, aerobic biodegradation reduces the toxic character of NAs. In this study, four commercial NAs and the...

Analysis of Naphthenic Acids in Filtered Oil Sands Process Water (OSPW) using LC/TOF with No Sample Preparation

Naphthenic acids (NAs) are water soluble weak acids, with the general chemical formula CnH2n+zO2, where n is the carbon number, z is referred to as hydrogen deficiency, is a negative even integer and is the number of hydrogen atoms that are lost as the number of rings in naphthenic acid increases. More than one isomer will exist for a given z homolog and the molecular weights differ by 2 mass u...

Potential of capillary electrophoresis mass spectrometry for the characterization and monitoring of amine-derivatized naphthenic acids from oil sands process-affected water.

Capillary electrophoresis coupled to mass spectrometry (CE-MS) was used for the analysis of naphthenic acid fraction compounds (NAFCs) of oil sands process-affected water (OSPW). A standard mixture of amine-derivatized naphthenic acids is injected directly onto the CE column and analyzed by CE-MS in less than 15min. Time of flight MS analysis (TOFMS), optimized for high molecular weight ions, s...