Bis(piperazine-1,4-diium) hexachloridobismuthate(III) chloride monohydrate
نویسندگان
چکیده
منابع مشابه
Bis(piperazine-1,4-diium) hexachloridobismuthate(III) chloride monohydrate
The crystal structure of the title compound, (C(4)H(12)N(2))(2)[BiCl(6)]Cl·H(2)O, consists of piperazinediium cations, [BiCl(6)](3-) anions, Cl(-) anions and uncoordinated water mol-ecules. The Bi(III) cation is coordinated by six Cl(-) anions in a slightly distorted octa-hedral geometry. The diprotonated piperazine ring adopts a chair conformation. In the crystal, extensive inter-molecular N-H...
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In the title salt, C(19)H(23)N(2)O(+)·Cl(-)·H(2)O, the ions and the water mol-ecule are held together by O-H⋯Cl, N-H⋯Cl, O-H⋯O, O-H⋯N and C-H⋯Cl hydrogen bonds, forming a three-dimensional framework. The vinyl group is disordered over two orientations with refined occupancies of 0.564 (16) and 0.436 (16). The cell parameters of the title compound have been reported previously [Griffiths (1952 ▶...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811045594