Carbonyl-carbonyl interactions in first-row transition metal complexes
نویسندگان
چکیده
منابع مشابه
Electrospray mass spectrometry of metal carbonyl complexes †
Methods are described for characterising neutral metal carbonyl complexes using electrospray mass spectrometry, by converting them into ions with suitable reagents. Ionisation techniques included addition of OMe generating [M 1 OMe] species, addition of Ag or Na ions giving the appropriate positive ion, abstraction of acidic hydrogen forming [M 2 H] ions, or (in rare cases) oxidation giving rad...
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Hormonal steroids, such as 17 -estradio1 derivatives, labelled with organometallic moieties have been synthesized and tested as markers for hormone receptor assay. Among the organometallic labels used were : Cr(C0) and Cr(C0)9(CS) which5can be attached to the arene A ring of the sterid ; Co9(C06 and Mo(rì -CH)9(C0)4 which can be bonded to acetylenic groups introduced at the 17c-p6sWton o the fl...
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.................................................................................................................... iii List of publications ..................................................................................................... v Abbreviations ............................................................................................................. ix
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[Rh(CO)2Cl] 2 reacts with 1,3-diphenylcyclopentadienyl sodium or tetraphenylcyclopentadienyl sodium with formation of (l,3-P h2C5H3)Rh(CO ) 2 (1) or (C5HPh4)Rh(CO )2 (2), respectively. The reaction of 1 or 2 with PPh3 yields the corresponding carbonyl(cyclopentadienyl)(triphenylphosphane)rhodium complexes (l,3 -P h 2C5H3)Rh(CO)(PPh3) (3) or (C5HPh4)Rh(CO)(PPh3) (4). The 'H and ' C reported and ...
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The photosensitivity of metal carbonyls has been known almost as long as the class of coordination compounds itself. Among no other group of inorganic compounds may one find so many light-sensitive materials. Hence photochemical reactions of metal carbonyls have found wide applications for synthetic purposes. However, whereas much research has been done to understand the thermal reactions," the...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2005
ISSN: 0108-7673
DOI: 10.1107/s010876730507995x