Comparison of six approaches to predicting droplet activation of surface active aerosol – Part 1: moderately surface active organics???????

نویسندگان

چکیده

Abstract. Surface active compounds (surfactants) are frequently found in atmospheric aerosols and droplets. As they adsorb to the surfaces of microscopic systems, surfactants can decrease aqueous surface tension simultaneously deplete bulk concentration. These processes may influence activation into cloud droplets investigation their role microphysics has been ongoing for decades. In this work, we have used six different models documented literature represent activity Köhler calculations droplet particles consisting one three moderately organics (malonic, succinic or glutaric acid) mixed with ammonium sulfate varying mass ratios. For each these organic acids, find that predict comparable properties at small fractions dry particles, despite large differences predicted degree bulk-to-surface partitioning. However, between model predictions same regarding both critical diameters supersaturations increase fraction particles. Comparison available experimental data shows assuming complete partitioning component (total depletion bulk) do not adequately high fractions. When reduced is also considered, somewhat improve. Models consider partial components yield results supersaturation data, even but bulk–surface strongly differ. This work highlights need use a thermodynamically consistent framework treat firm validation across wide range states relevant atmosphere.

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ژورنال

عنوان ژورنال: Atmospheric Chemistry and Physics

سال: 2022

ISSN: ['1680-7316', '1680-7324']

DOI: https://doi.org/10.5194/acp-22-2669-2022