Computational and experimental search for potential polyanionic K-ion cathode materials

Recent advances in first principles computational research of cathode materials for lithium-ion batteries.

To meet the increasing demands of energy storage, particularly for transportation applications such as plug-in hybrid electric vehicles, researchers will need to develop improved lithium-ion battery electrode materials that exhibit high energy density, high power, better safety, and longer cycle life. The acceleration of materials discovery, synthesis, and optimization will benefit from the com...

Polypyrrole hollow nanospheres: stable cathode materials for sodium-ion batteries.

Hollow polypyrrole (PPy) nanospheres with high sodium storage capacity as cathode materials for Na-ion batteries were reported. PPy hollow nanospheres demonstrated high current rate capacity and good cyclability. It was revealed by electrochemical testing and DFT calculation that the as-prepared PPy hollow nanospheres participate in reversible doping/de-doping reactions.

Comparative Issues of Cathode Materials for Li-Ion Batteries

After an introduction to lithium insertion compounds and the principles of Li-ion cells, we present a comparative study of the physical and electrochemical properties of positive electrodes used in lithium-ion batteries (LIBs). Electrode materials include three different classes of lattices according to the dimensionality of the Li ion motion in them: olivine, layered transition-metal oxides an...

Optimization of Layered Cathode Materials for Lithium-Ion Batteries

This review presents a survey of the literature on recent progress in lithium-ion batteries, with the active sub-micron-sized particles of the positive electrode chosen in the family of lamellar compounds LiMO₂, where M stands for a mixture of Ni, Mn, Co elements, and in the family of yLi₂MnO₃•(1 - y)LiNi½Mn½O₂ layered-layered integrated materials. The structural, physical, and chemical propert...

Manganese-based cathode materials for Li-ion batteries