Controlling the optical properties of hafnium dioxide thin films deposited with electron cyclotron resonance ion beam deposition

نویسندگان

چکیده

The effects of reactive and sputtering oxygen partial pressure on the structure, stoichiometry optical properties hafnium oxide (HfO2) thin films have been systematically investigated. electron cyclotron resonance ion beam deposition (ECR-IBD) technique was used to fabricate JGS-3 fused silica substrates. amorphous structure HfO2 were determined by X-ray Diffraction. Energy-dispersive Spectroscopy Rutherford Backscattering Spectrometry carried out for composition analysis, where this suggests formation over-stoichiometric films. data that O:Hf ratio ranges from 2.4 – 4.45 1 ECR-IBD fabricated in study. transmission reflectance spectra measured over a wide range wavelengths (λ = 185 3000 nm) utilizing spectrophotometer. analyzed an fitting software, which utilizes model modified O'Leary, Johnson Lim, extract properties, refractive index (n) bandgap energy (E0). By varying pressure, found be n 1.70 1.91, E0 5.6 6.0 eV. This study provides flexible method tuning coatings controlling mixture gas.

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ژورنال

عنوان ژورنال: Thin Solid Films

سال: 2023

ISSN: ['1879-2731', '0040-6090']

DOI: https://doi.org/10.1016/j.tsf.2023.139781