Development of New Metallocene Catalysts Used for High Temperature Polymerization. Ethylene-higher .ALPHA.-olefin Copolymerization by the Use of a New Metallocene IFZ Catalyst.
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چکیده
منابع مشابه
IN SITU SILICA SUPPORTED METALLOCENE CATALYSTS FOR ETHYLENE POLYMERIZATION
Bis(2-R-ind)ZrCl2 (R: H or phenyl) was supported on different types of silica by in situ impregnation method and used for ethylene polymerization. In this method, the step of catalyst loading on support was eliminated and common alkyl aluminum (triisobutylaluminum, TiBA) cocatalyst was used instead of expensive methyl aluminiumoxane (MAO) cocatalyst in the polymerization. The effect of surface ...
متن کاملAdvances in non-metallocene olefin polymerization catalysis.
B. Anionic Ligands 302 IX. Group 9 Catalysts 302 X. Group 10 Catalysts 303 A. Neutral Ligands 303 1. R-Diimine and Related Ligands 303 2. Other Neutral Nitrogen-Based Ligands 304 3. Chelating Phosphorus-Based Ligands 304 B. Monoanionic Ligands 305 1. [PO] Chelates 305 2. [NO] Chelates 306 3. Other Monoanionic Ligands 306 4. Carbon-Based Ligands 306 XI. Group 11 Catalysts 307 XII. Group 12 Catal...
متن کاملin situ silica supported metallocene catalysts for ethylene polymerization
bis(2-r-ind)zrcl2 (r: h or phenyl) was supported on different types of silica by in situ impregnation method and used for ethylene polymerization. in this method, the step of catalyst loading on support was eliminated and common alkyl aluminum (triisobutylaluminum, tiba) cocatalyst was used instead of expensive methyl aluminiumoxane (mao) cocatalyst in the polymerization. the effect of surface ...
متن کاملObservation of different catalytic activity of various 1-olefins during ethylene/1-olefin copolymerization with homogeneous metallocene catalysts.
This research aimed to investigate the copolymerization of ethylene and various 1-olefins. The comonomer lengths were varied from 1-hexene (1-C₆) up to 1-octadecene (1-C₁₈) in order to study the effect of comonomer chain length on the activity and properties of the polymer in the metallocene/MAO catalyst system. The results indicated that two distinct cases can be described for the effect of 1-...
متن کاملEffect of “Topotactic” Reduction Products on Catalytic Activity of Metallocene Catalyst for Olefin Polymerization
s of Doctor’s Thesises Effect of “Topotactic” Reduction Products on Catalytic Activity of Metallocene Catalyst for Olefin Polymerization Satoru Yamada † (Department of Chemistry for Materials)
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ژورنال
عنوان ژورنال: KOBUNSHI RONBUNSHU
سال: 2002
ISSN: 0386-2186,1881-5685
DOI: 10.1295/koron.59.133