Dielectric relaxations in ribose and deoxyribose supercooled water solutions
نویسندگان
چکیده
منابع مشابه
Permittivity and Dielectric Relaxations in Liquid-Ammonia Solutions
Dielectric constant and loss in liquid-ammonia solutions of alkali halides have been measured in the frequency range 0.7 — 70 GHz. At least one relaxation process exists in this frequency range in addition to the relaxation of the solvent molecules. The additional relaxation is ascribed to the orientational polarisation of ion pairs. The concentration of the ion pairs, calculated with a special...
متن کاملBiosynthesis of ribose and deoxyribose in Escherichia coli.
The studies reported here are concerned with the biosynthesis of ribose and deoxyribose in Escherichia coli R-2. When these studies were undertaken the evidence available allowed no general conclusions to be drawn as to a common biosynthetic pathway for the two pentoses. Since that time numerous studies have contributed to a better understanding of the problem. Tracer studies on the origin of r...
متن کاملVertical excitation energies for ribose and deoxyribose nucleosides
Vertical excitation energies for DNA and RNA nucleosides are determined with electron structure calculations using the time-dependent density functional theory (TDDFT) method at the B3LYP/6-311++G(d,p) level for nucleoside structures optimized at the same level of theory. The excitation energies and state assignments are verified using B3LYP/aug-cc-pVDZ level calculations. The nature of the fir...
متن کاملDynamic heterogeneities in supercooled water
We investigate dynamic heterogeneities in liquid water by performing molecular dynamics simulations of the SPC/E model. We find clusters of mobile molecules. We study the temperature and time dependence of the cluster size and find that clusters grow as temperature decreases and have a maximum size at the time scale corresponding to the escape of the molecules from the cage formed by neighborin...
متن کاملThermodynamics of supercooled water.
We review the available experimental information on the thermodynamic properties of supercooled water and demonstrate the possibility of modeling these thermodynamic properties on a theoretical basis. We show that by assuming the existence of a liquid-liquid critical point in supercooled water, the theory of critical phenomena can give an accurate account of the experimental thermodynamic-prope...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2009
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.3202215