Diffusion of Nonvolatile Metallic Elements in Graphite

Reentrant metallic behavior of graphite in the quantum limit.

Magnetotransport measurements performed on several well-characterized highly oriented pyrolitic graphite and single crystalline Kish graphite samples reveal a reentrant metallic behavior in the basal-plane resistance at high magnetic fields, when only the lowest Landau levels are occupied. The results suggest that the quantum Hall effect and Landau-level-quantization-induced superconducting cor...

Interlayer vacancy diffusion and coalescence in graphite

Due to the layered nature of graphite, the migration and interaction of point defects in the graphite crystal structure are highly anisotropic, and it is usually assumed that individual mobile lattice vacancies are confined to diffuse on a single plane. We present the results of ab initio calculations based on density functional theory which demonstrate that vacancies can, in fact, move between...

Residual Resistivity of Some Metallic Elements

In the present article, the residual resistivity of some metallic elements of the periodic table is reported on the basis of model potential formalism. Ashcroft's well known empty core (EMC) model potential is explored first time with five different types of the local field correction functions proposed by Hartree (H), Taylor (T), Ichimaru-Utsumi (IU), Farid et al (F) and Sarkar et al (S) to in...

Energetics of defects and diffusion mechanisms in graphite.

First-principles simulations of boron diffusion in graphite.

Boron strongly modifies electronic and diffusion properties of graphite. We report the first ab initio study of boron interaction with the point defects in graphite, which includes structures, thermodynamics, and diffusion. A number of possible diffusion mechanisms of boron in graphite are suggested. We conclude that boron diffuses in graphite by a kick-out mechanism. This mechanism explains th...