Direct conversion of sec-phosphine oxides to sec-phosphine-boranes using BH3
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چکیده
منابع مشابه
Simple unprecedented conversion of phosphine oxides and sulfides to phosphine boranes using sodium borohydride.
A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride.
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ژورنال
عنوان ژورنال: Tetrahedron Letters
سال: 2021
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2021.152837