Driving Force for Oxygen‐Atom Transfer by Heme‐Thiolate Enzymes
نویسندگان
چکیده
منابع مشابه
Driving force for oxygen-atom transfer by heme-thiolate enzymes.
The heme-thiolate peroxygenase from Agrocybe aegerita (AaeAPO, EC 1.11.2.1) is a versatile biocatalyst and cytochrome P450 analogue which catalyzes a variety of oxygenation reactions with high efficiency and selectivity. Our recent kinetic characterization of AaeAPO-catalyzed reactions has shown that AaeAPO compound I is an oxo-Fe porphyrin radical cation. The reactivity of AaeAPO-I toward a pa...
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2013
ISSN: 0044-8249,1521-3757
DOI: 10.1002/ange.201302137