Effect of Surface Interactions on Anodic Stripping Analysis Using Platinum Electrodes
نویسندگان
چکیده
منابع مشابه
Heavy Metal Analysis by Anodic Stripping Voltammetry
Let’s say that you wanted to determine the heavy metal identities and concentrations in sediment and suspended solid samples obtained from present day Lake Nakuru. What technique would you use for this determination? You could use Atomic Absorption Spectroscopy (AAS) as was done in the article (Nelson 1998), but another technique, which is particularly good at detecting metals at the ppb level ...
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The high mass transport caused by ultrasonic radiation in the preconcentration of trace metal species in anodic stripping voltammetry (ASV), leads to an order of magnitude enhancement in sensitivity. A Nafion-coated mercury thin-film working electrode is placed in a specially designed small-volume sonovoltammetric cell. The preparation and curing procedure for the Nafion film on a glassy carbon...
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Zinc (Zn) homeostasis is required for a functional immune system. Critically ill patients often exhibit decreased Zn serum concentrations and could potentially benefit from Zn supplementation as a therapeutic strategy. However, the conventional approaches to monitoring Zn are time consuming and costly. This work reports on detection of Zn by anodic stripping voltammetry (ASV) on bismuth electro...
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Numerical simulations based on the time dependent backward implicit method are used to develop the theory of anodic stripping voltammetry carried out under hydrodynamic conditions using mercury thin film wall-jet electrodes. The peak shape is shown to be highly sensitive both to electrolyte flow rate and to the potential sweep rate. The simulations permit visualization of concentrations both in...
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The application of batch injection analysis to the determination of trace metals in samples of volume s 100 ~1 by square wave anodic stripping voltammetry has been investigated in detail, using a programmable electronic micropipette. The in situ formation of a mercury film on a glassy carbon electrode substrate, the influence of preconcentration time, injection rate and injected volume of analy...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1972
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.21.1290