Enzymatic kinetic resolution of desmethylphosphinothricin indicates that phosphinic group is a bioisostere of carboxyl group
نویسندگان
چکیده
منابع مشابه
faculty of psychology and social sciences group of anthropology master thesis in major of anthropology
چکیده پایان نامه (شامل خلاصه، اهداف، روش های اجرا و نتایج به دست آمده): کار جمع آوری گو یش های محلی در سال های اخیر شتاب امیدوار کننده ای به خود گرفته است. شاید از بارزترین اهداف جمع آوری گویش های مختلف، ثبت و ضبط آن، جلوگیری از نابودی و مهمتر از همه حل مشکلات دستوری زبان رسمی باشد. دقت در فرآیند های زبانی گویش های محلی نوع ارتباط مردم نواحی مختلف با پیرامون نشان را به ما نشان خواهد داد. از س...
A generalization of the probability that the commutator of two group elements is equal to a given element
The probability that the commutator of two group elements is equal to a given element has been introduced in literature few years ago. Several authors have investigated this notion with methods of the representation theory and with combinatorial techniques. Here we illustrate that a wider context may be considered and show some structural restrictions on the group.
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Every Seifert Fibre Group is the lift of a Fuchsian group to the universal covering group of PSL (2,R). From this, we work out a form of presentation for such a group. With the calculation of the Euler number, we can establish the presentation of the derived group of a Seifert Fibre Group
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The reaction of furylacrylic acid with cyclopentadiene in toluene gave the expected Diels-Alder endo-and exo-adductsin -1 : 1 ratio. The adducts were separated by iodolactonization method to provide 3-endo-(2'-furyl) bicyclo 12.2.11 hept-5-ene- 2-exo-carboxylic acid and 3-exo-(2'-fury1)bicyclo 12.2.11 hept-5-ene-2-endocarboxylic acid. Esterification of these acids by MeI / HMPA gave the exp...
متن کاملThe enzymatic synthesis of fatty acid methyl esters by carboxyl group alkylation.
The reaction was studied by incubation of fatty acid with S-adenosyhnethionine-methylJ4C and isolation of the labeled ester. This was characterized by thin layer and gas-liquid chromatography and by isolation of labeled methanol from alkaline hydrolysates of the ester. Of several substrates tested only S-adenosylmethionine was an effective methyl donor (K,,, = 2.5 X 10F5 M) and oleic acid was t...
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ژورنال
عنوان ژورنال: Communications Chemistry
سال: 2020
ISSN: 2399-3669
DOI: 10.1038/s42004-020-00368-z