Exact solution to ideal chain with fixed angular momentum

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Exact solution to ideal chain with fixed angular momentum.

The statistical mechanics of a noninteracting polymer chain in the limit of a large number of monomers is considered when the total angular momentum L is fixed. The radius of gyration for a ring polymer in this situation is derived exactly in closed form by functional integration techniques. Even when L=0 the radius of gyration differs from that of a random walk by a prefactor of order unity. T...

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ژورنال

عنوان ژورنال: Physical Review E

سال: 2008

ISSN: 1539-3755,1550-2376

DOI: 10.1103/physreve.77.051804