Exploiting dense shell/packing principles to invoke stereoselectivity in a reaction accelerated by a chiral dendrimer
نویسندگان
چکیده
منابع مشابه
Exploiting dense shell/packing principles to invoke stereoselectivity in a reaction accelerated by a chiral dendrimer.
As dendrimers approach their dense shell or dense packed limit, a certain amount of conformational organization exists. Any substrate binding within the dendrimer's external layer will experience the same organizational effects. This paper describes how these effects can be exploited towards stereocontrol with respect to binding and reactivity.
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2013
ISSN: 1359-7345,1364-548X
DOI: 10.1039/c3cc43830a