Front Cover: Bismuth Cations: Fluoride Ion Abstraction, Isocyanide Coordination, and Impact of Steric Bulk on Lewis Acidity (Chem. Eur. J. 30/2023)
نویسندگان
چکیده
Bi Lewis acidic: Donor-free cationic bismuth compounds readily coordinate basic substrates including arenes, phosphanes, and isonitriles, degrade the weakly coordinating counter-anion [PF6]–. Counterintuitively, an increase in steric bulk around can acidity. In graphic, a kraken grabs substrates, solving scientific puzzles about bismuth-based More information be found Research Article by C. von Hänisch, Lichtenberg co-workers (DOI: 10.1002/chem.202204012).
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ژورنال
عنوان ژورنال: Chemistry: A European Journal
سال: 2023
ISSN: ['0947-6539', '1521-3765']
DOI: https://doi.org/10.1002/chem.202301353