Front Cover Picture: Chiral Iron Complexes in Asymmetric Organic Transformations (Adv. Synth. Catal. 4/2022)

Cover Picture.

Chiral poly-rare earth metal complexes in asymmetric catalysis

Asymmetric catalysis is a powerful component of modern synthetic organic chemistry. To further broaden the scope and utility of asymmetric catalysis, new basic concepts for the design of asymmetric catalysts are crucial. Because most chemical reactions involve bond-formation between two substrates or moieties, high enantioselectivity and catalyst activity should be realized if an asymmetric cat...

Transition metal complexes in organic synthesis. Part 47.1 Organic synthesis via tricarbonyl(h4-diene)iron complexes

The protection of conjugated dienes by coordination to the tricarbonyliron fragment offers many potential applications of the resulting complexes to organic synthesis. The preparation of tricarbonyl(h4-1,3-diene)iron complexes is readily achieved by a 1-azabutadiene-catalyzed complexation of the free ligands. An asymmetric catalytic complexation of prochiral cyclohexa-1,3-dienes with pentacarbo...

Proceedings Front Cover 8X10

The integrated Rule Oriented Data Management System (iRODS) is a policy-driven data management system that is starting to be used by projects with large data volume requirements that require a highly available system. In this paper we describe an approach to provide a Highly Availability load-balanced iRODS System (HAIRS). We also describe the advantages and disadvantages of the approach and fu...

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