Functionalization oftrans-Decalin. II. A Synthesis ofdl-Isopetasol fromtrans-5-Oxodecalin-8a,2-carbolactone
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چکیده
منابع مشابه
Total synthesis of antimalarial diterpenoid (+)-kalihinol A.
Total synthesis of antimalarial diterpenoid (+)-kalihinol A, isolated from marine sponge Acanthella sp., is achieved. This total synthesis involves regioselective alkylation of an epoxide, construction of a tetrahydropyran ring by iodo-etherification, construction of a cis-decalin ring by intramolecular Diels-Alder reaction, isomerization of cis-decalin to trans-decalin, and subsequent function...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1979
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.52.861