Gas-liquid flow characterization and mass transfer study in a microreactor for oligomerization catalyst testing
نویسندگان
چکیده
The acceleration of the development ethylene oligomerization processes by homogeneous catalysis requires a complete characterization catalytic system. This work proposes to use segmented gas-liquid flow in microchannels achieve high experimental throughput for catalyst testing. Gas-liquid was studied order validate microreactor setup. Results showed that bubble and slug lengths vary linearly with superficial velocities ratio following Garstecki et al. model [21]. impact lateral feed Taylor explored mimic an test. experiments volume liquid slugs increased proportionally additional rate, thereby suggesting majority is ultimately retained slug. A study mass transfer volumetric coefficient between 0.27 0.55 s−1. These values lead Hatta number < 0.5, thus confirming possibility conducting reaction chemical kinetic regime. Finally, test performed continuous system can be used screening purpose.
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ژورنال
عنوان ژورنال: Chemical Engineering and Processing
سال: 2021
ISSN: ['1873-3204', '0255-2701']
DOI: https://doi.org/10.1016/j.cep.2021.108476