Generalized rank annihilation method. II: Bias and variance in the estimated eigenvalues

Generalized Rank Annihilation Method . 111 : Practical Implementation

Derivation of the generalized rank annihilation method (GRAM)

Introduction The generalized rank annihilation method (GRAM) is a method for curve resolution and calibration that requires only a single calibration sample to obtain the socalled second-order advantage, i.e., it can determine the analyte of interest in the presence of unsuspected interferences [1]. GRAM is only one of many competing methods that can be applied to this particular data set-up. H...

A mathematically simple method based on denition for computing eigenvalues, generalized eigenvalues and quadratic eigenvalues of matrices

In this paper, a fundamentally new method, based on the denition, is introduced for numerical computation of eigenvalues, generalized eigenvalues and quadratic eigenvalues of matrices. Some examples are provided to show the accuracy and reliability of the proposed method. It is shown that the proposed method gives other sequences than that of existing methods but they still are convergent to th...

Simultaneous spectrofluorometric determination of piroxicam and pyridoxine using generalized rank annihilation method.

The application of generalized rank annihilation method (GRAM) to the analysis of fluorescence excitation-emission matrices of mixtures of piroxicam and pyridoxine is described. The input of GRAM consists of two bilinear data matrices, i.e. one for unknown and one for the calibration sample. The excitation wavelength range was from 290 to 340 nm and the emission was recorded from 370 to 560 nm....

Inferences on the Generalized Variance under Normality

Generalized variance is applied for determination of dispersion in a multivariate population and is a successful measure for concentration of multivariate data. In this article, we consider constructing confidence interval and testing the hypotheses about generalized variance in a multivariate normal distribution and give a computational approach. Simulation studies are performed to compare thi...