Hybridization Trends for Main Group Elements and Expanding the Bent’s Rule Beyond Carbon: More than Electronegativity
نویسندگان
چکیده
منابع مشابه
Electronegativity Equalization and the Electronic Structure of Polyhedral Clusters of Main-Group Atoms
The concept of the equalization of atomic electronegativities accompanying molecule formation is applied to a study of the electronic structure of polyhedral clusters of main-group atoms such as Ge, Sn, Pb, TI, and Bi. Emphasis is placed upon charged clusters such as Sn9-,Pb:-(x =0+9), Sn+,Ge;-, Sn8-= Pb,T15-, Sn,Bii-, SnTei-, etc. The role of the relativistic spin-orbit splitting of an np shel...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry A
سال: 2014
ISSN: 1089-5639,1520-5215
DOI: 10.1021/jp502472u