Incorporation of mixed metals into SAPO-34 frameworks by the dry-gel conversion method using mixed templates: investigating catalysts characterisation and performance

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Characterization and optimization of SAPO-34 catalysts synthesized by mixed templates in MTO reaction

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Synthesis of SAPO-34 catalysts via controlled crystal growth

Introduction SAPO-34 is a silicoaluminophosphate zeolite with 8-membered ring windows (~0.38nm) displaying chabazite structure. SAPO-34 is an efficient catalyst showing improved catalytic performance in reactions such as methanol conversion to olefins [1], oxidative dehydrogenation of propane [2], conversion of light alkenes [3]. Its catalytic properties are mainly attributed to its mild acidit...

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Organosilane surfactant-directed synthesis of hierarchical porous SAPO-34 catalysts with excellent MTO performance.

Using an organosilane surfactant as the mesopore director, hierarchical porous silicoaluminophosphate SAPO-34 is obtained as an assembly of nanocrystallites intergrown into cubic micrometer-sized crystals, which show excellent performance in MTO reactions with a remarkably prolonged catalyst lifetime and enhanced selectivity of ethylene and propylene compared to the conventional microporous SAP...

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ژورنال

عنوان ژورنال: Journal of Experimental Nanoscience

سال: 2016

ISSN: 1745-8080,1745-8099

DOI: 10.1080/17458080.2016.1184767