Ion selectivity in capacitive deionization with functionalized electrode: Theory and experimental validation
نویسندگان
چکیده
منابع مشابه
Two-Dimensional Porous Electrode Model for Capacitive Deionization
Ion transport in porous conductive materials is of great importance in a variety of electrochemical systems including batteries and supercapacitors. We here analyze the coupling of flow and charge transport and charge capacitance in capacitive deionization (CDI). In CDI, a pair of porous carbon electrodes is employed to electrostatically retain and remove ionic species from aqueous solutions. W...
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In capacitive deionization (CDI) water is desalinated by applying an electrical field between two porous electrodes placed on either side of a spacer channel that transports the aqueous solution. In this work we investigate the equilibrium salt adsorption and the dynamic development of the effluent salt concentration in time, both as function of spacer and electrode thicknesses. The electrode t...
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Membrane capacitive deionization (MCDI) is a technology for water desalination based on applying an electrical field between two oppositely placed porous electrodes. Ions are removed from the water flowing through a channel in between the electrodes and are stored inside the electrodes. Ion-exchange membranes are placed in front of the electrodes allowing for counterion transfer from the channe...
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We explored the energy loss mechanisms in capacitive deionization (CDI). We hypothesize that resistive and parasitic losses are two main sources of energy losses. We measured contribution from each loss mechanism in water desalination with constant current (CC) charge/discharge cycling. Resistive energy loss is expected to dominate in high current charging cases, as it increases approximately l...
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Membrane capacitive deionization (MCDI) is a promising technique to achieve the desalination. This novel technique can largely improve the desalination efficiency of capacitive deionization (CDI) by introducing ion-exchange membranes into CDI. This paper presents a comparative study on the electrosorptive performances of CDI and MCDI based on single walled carbon nanotubes electrodes in NaCl so...
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ژورنال
عنوان ژورنال: Water Research X
سال: 2018
ISSN: 2589-9147
DOI: 10.1016/j.wroa.2018.100008