Kinetic studies of a phenoxy radical intermediate using optical and electron spin resonance spectroscopy
نویسندگان
چکیده
منابع مشابه
MAGNETISATION AND ELECTRON SPIN RESONANCE STUDIES OF TETRAHEDRAL AMORPHOUS CARBON
The magnetisation and electron spin resonance (ESR) spectrum of two specimens of tetrahedral amorphous carbon (ta-C), deposited from a filtered cathodic arc, were measured over a wide temperature range. The magnetisation was found to consist of superparamagnetic, paramagnetic and diamagnetic contributions. The superparamagnetic contribution resembled that recently found in carbon prepared from ...
متن کاملmagnetisation and electron spin resonance studies of tetrahedral amorphous carbon
the magnetisation and electron spin resonance (esr) spectrum of two specimens of tetrahedral amorphous carbon (ta-c), deposited from a filtered cathodic arc, were measured over a wide temperature range. the magnetisation was found to consist of superparamagnetic, paramagnetic and diamagnetic contributions. the superparamagnetic contribution resembled that recently found in carbon prepared from ...
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Electron spin resonance (ESR) spectroscopy's affinity for detecting paramagnetic free radicals, or spins, has been increasingly employed to examine a large variety of biochemical interactions. Such paramagnetic species are broadly found in nature and can be intrinsic (defects in solid-state materials systems, electron/hole pairs, stable radicals in proteins) or, more often, purposefully introdu...
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The breakdown of cumene hydroperoxide and peroxidized fatty acids by iron is shown, by use of the spin trap 5,5-dimethyl-l-pyrroline-N-oxide, to be sensitive to (a) the oxidation state of the metal and (b) the nature of the chelating ligands. The initial step in the Fe2+-catalysed breakdown is the production of an alkoxyl radical by one-electron reduction, and this type of radical has been succ...
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ion and subsequent deprotonation gives rise to phenoxy radicals, which play a pivotal role in lignin chemistry. Overall spin trapping systems could be powerful tools to understand the radical intermediates involved in lignin chemistry. In Table 4 our data on spin trap experiments with DIPPMPO and different phenols are shown. There are different oxidation systems for the generation of phenoxy ra...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1967
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v67-489