Laboratory rotational ground state transitions of NH3D+and CF+

Line strengths of rovibrational and rotational transitions within the X³Σ⁻ ground state of NH.

A new line list for rovibrational and rotational transitions, including fine structure, within the NH X³Σ⁻ ground state has been created. It contains line intensities in the form of Einstein A and f-values, for all possible bands up to v' = 6, and for J up to between 25 and 44. The intensities are based on a new dipole moment function (DMF), which has been calculated using the internally contra...

Line strengths of rovibrational and rotational transitions within the X 3 ground state of NH

Ground state overlap and quantum phase transitions.

We present a characterization of quantum phase transitions in terms of the the overlap function between two ground states obtained for two different values of external parameters. On the examples of the Dicke and XY models, we show that the regions of criticality of a system are marked by the extremal points of the overlap and functions closely related to it. Further, we discuss the connections...

Note: Improved line strengths of rovibrational and rotational transitions within the X(3)Σ(-) ground state of NH.

Recently, a line list including positions and transition strengths was published for the NH X(3)Σ(-) rovibrational and rotational transitions. The calculation of the transition strengths requires a conversion of transition matrix elements from Hund's case (b) to (a). The method of this conversion has recently been improved during other work on the OH X(2)Π rovibrational transitions, by removing...

Laboratory Measurement of the Pure Rotational Transitions of the HCNH and its Isotopic Species

The pure rotational transitions of the protonated hydrogen cyanide ion, HCNH, and its isotopic species, HCND and DCND, were measured in the 107 482 GHz region with a source modulated microwave spectrometer. The ions were generated in the cell with a magnetically confined dc-glow discharge of HCN and/or DCN. The rotational constant B0 and the centrifugal distortion constant D0 for each ion were ...