Lanthanides and Actinides in Ionic Liquids
نویسندگان
چکیده
منابع مشابه
Lanthanides and Actinides
The application of quantum chemistry to systems containing atoms of the lanthanide (57La 71Lu) and/or actinide (90Th 103Lr) series is a considerable challenge and has been attempted only by a comparatively small number of researchers. Several complications, some of which will be described in the following, prevent standard quantum chemical approaches from being successful in this field in all r...
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Liquid-liquid extraction of lanthanides from aqueous solutions into ionic liquids (ILs) has been investigated using N,N,N',N'-tetra(n-octyl)diglycolamide (TODGA) as an extractant, and compared with that in the isooctane system. Application of ILs as the extracting phase provided unprecedented enhancement of the extraction performance of TODGA for lanthanides compared with that of the isooctane ...
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In an earlier article, atomic radii of elements of Groups 1A 8A were shown to be proportional to their Bohr radii obtained from the first ionization potentials and the constants of proportionality were shown to be simple functions of the Golden ratio. Here it is shown that the above finding holds also for elements of Groups 1B 8B including Lanthanides and Actinides. All the relevant data are pr...
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ژورنال
عنوان ژورنال: Chemical Reviews
سال: 2007
ISSN: 0009-2665,1520-6890
DOI: 10.1021/cr050979c